Titelbild: A Stable and Conductive Covalent Organic Framework with Isolated Active Sites for Highly Selective Electroreduction of Carbon Dioxide to Acetate (Angew. Chem. 36/2022)
نویسندگان
چکیده
Die Elektroreduktion von CO2 zu Acetat ist eine vielversprechende Strategie zur Speicherung erneuerbarer Energie, jedoch fällt normalerweise als Nebenprodukt an. Pei-Qin Liao und Mitarbeiter berichten in ihrer Zuschrift (e202206470) über ein kovalentes organisches Gerüst mit isolierten aktiven Zentren für die hochselektive Acetat. Das aktive Kupfer-Phthalocyanin-Zentrum hoher Elektronendichte begünstigt den Schlüsselschritt der C-C-Kupplung *CH3 Bildung unterdrückt Kupplung *CO oder *CHO Ethylen Ethanol.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2022
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202210257